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Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones - Corinna Reisinger
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Corinna Reisinger:
Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones - nouveau livre

ISBN: 9783642281174

[ED: Buch], [PU: Springer-Verlag GmbH], Neuware - Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic ,beta-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro peroxi dation of ,beta-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date. -, [SC: 0.00], Neuware, gewerbliches Angebot, 247x163x20 mm, [GW: 558g]

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Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones - Corinna Reisinger
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Corinna Reisinger:
Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones - nouveau livre

ISBN: 9783642281174

[ED: Buch], [PU: Springer-Verlag GmbH], Neuware - Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic ,beta-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro peroxi dation of ,beta-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date., [SC: 0.00], Neuware, gewerbliches Angebot, 247x163x20 mm, [GW: 558g]

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Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones - Corinna Reisinger
Livre non disponible
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Corinna Reisinger:
Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones - nouveau livre

ISBN: 9783642281174

[ED: Buch], [PU: Springer-Verlag GmbH], Neuware - Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic ,beta-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro peroxi dation of ,beta-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date., [SC: 0.00], Neuware, gewerbliches Angebot, 247x163x20 mm, [GW: 558g]

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Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones - Corinna Reisinger
Livre non disponible
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Corinna Reisinger:
Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones - nouveau livre

ISBN: 9783642281174

[ED: Buch], [PU: Springer-Verlag GmbH], - Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic , -unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro peroxi dation of , -enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date. -, [SC: 0.00]

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Epoxidations and Hydroperoxidations of α,β-Unsaturated Ket - Corinna Reisinger
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Corinna Reisinger:
Epoxidations and Hydroperoxidations of α,β-Unsaturated Ket - edition reliée, livre de poche

2012, ISBN: 9783642281174

ID: 22304389

An Approach through Asymmetric Organocatalysis, [ED: 2011], Hardcover, Buch, [PU: Springer Berlin]

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Détails sur le livre

Informations détaillées sur le livre - Epoxidations and Hydroperoxidations of a,ß-Unsaturated Ketones


EAN (ISBN-13): 9783642281174
ISBN (ISBN-10): 3642281176
Version reliée
Date de parution: 2012
Editeur: Springer-Verlag GmbH
255 Pages
Poids: 0,558 kg
Langue: Englisch

Livre dans la base de données depuis 20.03.2007 11:44:05
Livre trouvé récemment le 25.12.2016 18:06:48
ISBN/EAN: 3642281176

ISBN - Autres types d'écriture:
3-642-28117-6, 978-3-642-28117-4


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