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Radical Reactions of Fullerenes and their Derivatives - O. Kalina
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O. Kalina:
Radical Reactions of Fullerenes and their Derivatives - nouveau livre

ISBN: 9781402001765

[ED: Buch], [PU: Springer], Neuware - The discovery of fullerenes, species belonging to the electronodeficient polyalkenes with weakly conjugated double bonds, has opened novel opportunities for the radical chemistry. Pioneering study in this field was performed by P. J. Krusic, E. Wasserman, P. N. Keizer, J. R. Morton, and K. F. Preston (Science, 1991, 254, 1184). The fullerenyl radical adducts formed via addition of atoms or free radicals to fullerenes have no analogs in organic chemistry. In fact, radicals in which the unpaired electrons are delocalized over the surface of a sphere or ellipsoid have never been studied before. The unusual character of the fullerenyl radicals is also due to the fact that they occupy a sort of intermediate position between the planar and tetrahedral radicals. Thus, the elucidation of the characteristic features of fullerenyl radicals and their reactivity by EPR spectroscopy, and the comparison of the results with those of quantum-chemical studies are of fundamental importance. Isolation of the products from homolytic reactions of fullerenes in bulk amounts opens the door to large-scale preparation of new organic and organoelement derivatives of including biologically active ones. Radical reactions of fullerenes find wide application in the synthesis of fullere- containing polymers with valuable photophysical characteristics. Ferromagnetism of the complex of with tetra(dimethylamino)ethylene found lends impetus to a search of novel methods for preparation of biradicals one unpaired electron of those is located on the fullerene cage while the other retained by the addend. -, DE, [SC: 0.00], Neuware, gewerbliches Angebot, 235x155x17 mm, 212, [GW: 485g], offene Rechnung (Vorkasse vorbehalten), PayPal, Banküberweisung, Interntationaler Versand

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Radical Reactions of Fullerenes and their Derivatives - O. Kalina
Livre non disponible
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O. Kalina:
Radical Reactions of Fullerenes and their Derivatives - nouveau livre

ISBN: 9781402001765

[ED: Buch], [PU: Springer], Neuware - The discovery of fullerenes, species belonging to the electronodeficient polyalkenes with weakly conjugated double bonds, has opened novel opportunities for the radical chemistry. Pioneering study in this field was performed by P. J. Krusic, E. Wasserman, P. N. Keizer, J. R. Morton, and K. F. Preston (Science, 1991, 254, 1184). The fullerenyl radical adducts formed via addition of atoms or free radicals to fullerenes have no analogs in organic chemistry. In fact, radicals in which the unpaired electrons are delocalized over the surface of a sphere or ellipsoid have never been studied before. The unusual character of the fullerenyl radicals is also due to the fact that they occupy a sort of intermediate position between the planar and tetrahedral radicals. Thus, the elucidation of the characteristic features of fullerenyl radicals and their reactivity by EPR spectroscopy, and the comparison of the results with those of quantum-chemical studies are of fundamental importance. Isolation of the products from homolytic reactions of fullerenes in bulk amounts opens the door to large-scale preparation of new organic and organoelement derivatives of including biologically active ones. Radical reactions of fullerenes find wide application in the synthesis of fullere- containing polymers with valuable photophysical characteristics. Ferromagnetism of the complex of with tetra(dimethylamino)ethylene found lends impetus to a search of novel methods for preparation of biradicals one unpaired electron of those is located on the fullerene cage while the other retained by the addend., DE, [SC: 0.00], Neuware, gewerbliches Angebot, 235x155x17 mm, 212, [GW: 485g], PayPal, offene Rechnung, Banküberweisung, sofortueberweisung.de, Interntationaler Versand

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Radical Reactions of Fullerenes and their Derivatives - O. Kalina
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O. Kalina:
Radical Reactions of Fullerenes and their Derivatives - nouveau livre

ISBN: 9781402001765

[ED: Buch], [PU: Springer], Neuware - The discovery of fullerenes, species belonging to the electronodeficient polyalkenes with weakly conjugated double bonds, has opened novel opportunities for the radical chemistry. Pioneering study in this field was performed by P. J. Krusic, E. Wasserman, P. N. Keizer, J. R. Morton, and K. F. Preston (Science, 1991, 254, 1184). The fullerenyl radical adducts formed via addition of atoms or free radicals to fullerenes have no analogs in organic chemistry. In fact, radicals in which the unpaired electrons are delocalized over the surface of a sphere or ellipsoid have never been studied before. The unusual character of the fullerenyl radicals is also due to the fact that they occupy a sort of intermediate position between the planar and tetrahedral radicals. Thus, the elucidation of the characteristic features of fullerenyl radicals and their reactivity by EPR spectroscopy, and the comparison of the results with those of quantum-chemical studies are of fundamental importance. Isolation of the products from homolytic reactions of fullerenes in bulk amounts opens the door to large-scale preparation of new organic and organoelement derivatives of including biologically active ones. Radical reactions of fullerenes find wide application in the synthesis of fullere- containing polymers with valuable photophysical characteristics. Ferromagnetism of the complex of with tetra(dimethylamino)ethylene found lends impetus to a search of novel methods for preparation of biradicals one unpaired electron of those is located on the fullerene cage while the other retained by the addend., DE, [SC: 0.00], Neuware, gewerbliches Angebot, FixedPrice, 212, [GW: 485g], offene Rechnung (Vorkasse vorbehalten), PayPal, Banküberweisung

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Radical Reactions of Fullerenes and Their Derivatives - Oleg Kalina; Boris Tumanskii
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Oleg Kalina; Boris Tumanskii:
Radical Reactions of Fullerenes and Their Derivatives - livre d'occasion

1991, ISBN: 1402001762

ID: 3128728

The discovery of fullerenes, species belonging to the electronodeficient polyalkenes with weakly conjugated double bonds, has opened novel opportunities for the radical chemistry. Pioneering study in this field was performed by P. J. Krusic, E. Wasserman, P. N. Keizer, J. R. Morton, and K. F. Preston (Science, 1991, 254, 1184). The fullerenyl radical adducts formed via addition of atoms or free radicals to fullerenes have no analogs in organic chemistry. In fact, radicals in which the unpaired electrons are delocalized over the surface of a sphere or ellipsoid have never been studied before. The unusual character of the fullerenyl radicals is also due to the fact that they occupy a sort of intermediate position between the planar and tetrahedral radicals. Thus, the elucidation of the characteristic features of fullerenyl radicals and their reactivity by EPR spectroscopy, and the comparison of the results with those of quantum-chemical studies are of fundamental importance. Isolation of the products from homolytic reactions of fullerenes in bulk amounts opens the door to large-scale preparation of new organic and organoelement derivatives of including biologically active ones. Radical reactions of fullerenes find wide application in the synthesis of fullere- containing polymers with valuable photophysical characteristics. Ferromagnetism of the complex of with tetra(dimethylamino)ethylene found lends impetus to a search of novel methods for preparation of biradicals one unpaire science,science and math,science and scientists,science and technology Science & Math, Springer

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Radical Reactions of Fullerenes and Their Derivatives - Boris Tumanskii; Oleg Kalina
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Boris Tumanskii; Oleg Kalina:
Radical Reactions of Fullerenes and Their Derivatives - edition reliée, livre de poche

2001, ISBN: 9781402001765

ID: 3406382

Hardcover, Buch, [PU: Kluwer Academic Publishers]

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Détails sur le livre
Radical Reactions of Fullerenes and their Derivatives

The discovery of fullerenes has opened novel opportunities for radical chemistry. The fullerenyl radical adducts formed via addition of atoms or free radicals to fullerenes have no analogs in organic chemistry. Thus, the elucidation of the characteristic features of fullerenyl radicals and their reactivity by EPR spectroscopy is of fundamental importance. Isolation of the products from homolytic reactions of fullerenes in bulk amounts opens the door to large-scale preparation of new organic and organoelement derivatives of C60, including biologically active ones. Radical reactions of fullerenes find wide application in the synthesis of fullerene-containing polymers with valuable photophysical characteristics. Ferromagnetism of the complex of C60 with tetra(dimethylamino)ethylene lends impetus to a search for novel methods for preparation of biradicals, with one unpaired electron located on the fullerene cage and the other retained by the addend. This book covers the results of studies on homolytic reactions of fullerenes, the structures and reactivities of fullerenyl radicals performed by EPR, quantum-chemical, and other methods. Examples of the application of radical reactions of fullerenes in the synthesis and typical methods for their investigation are given. This book is intended for researchers working in chemistry of homolytic reactions as well as for fullerene scientists.

Informations détaillées sur le livre - Radical Reactions of Fullerenes and their Derivatives


EAN (ISBN-13): 9781402001765
ISBN (ISBN-10): 1402001762
Version reliée
Date de parution: 2001
Editeur: Springer-Verlag GmbH
212 Pages
Poids: 0,479 kg
Langue: eng/Englisch

Livre dans la base de données depuis 07.10.2007 07:14:04
Livre trouvé récemment le 15.09.2017 12:44:33
ISBN/EAN: 1402001762

ISBN - Autres types d'écriture:
1-4020-0176-2, 978-1-4020-0176-5


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